Extractive-liquid sampling electron ionization-mass spectrometry (E-LEI-MS): a new powerful combination for direct analysis

Several prototype adjustments were tried before achieving the final configuration. Several operating parameters were considered, such as capillary dimensions, aspiration rate, solvent delivery mode, type of valve used as an on/off device, and sampling mode. The optimized system configuration, described in the following section, was tested with different matrices to demonstrate its performance and versatility. Working parameters were set depending on the sample nature and application field. The application workflow was designed to demonstrate the system’s capability to operate in several…

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